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1. The Solvent Method: Beans are soaked in a liquid that binds to caffeine. This process is fast and effective, but less common in specialty coffee. |
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2. The Swiss Water Process: Uses only water and filters to remove caffeine. The results are clean, chemical-free and flavour-friendly coffee beans. |
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3. CO2 Method: High-pressure carbon dioxide extracts caffeine precisely. This process helps keep delicate aromas intact. |
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4. Sugar Cane / EA Method: The beans are steamed, then immersed in a water-ethyl acetate bath where sugarcane-derived EA selectively binds and removes the caffeine. |
Decaffeination in Depth.
1. Solvent decaffeination method:
The solvent method removes caffeine from green, unroasted coffee using a selective solvent—usually ethyl acetate or methylene chloride.
How it works:
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Hydration
The green beans are gently steamed or soaked. This opens their cellular structure and makes the caffeine accessible. -
Caffeine extraction
The beans are repeatedly washed with the solvent. It bonds primarily with the caffeine and draws it out of the beans. -
Solvent removal
The caffeine-rich solvent is drained away. The beans are then thoroughly steamed and rinsed to remove residual solvent. -
Drying
The decaffeinated beans are carefully dried back to a stable moisture level. -
Roasting
The beans are roasted normally. Roasting temperatures are substantially higher than the boiling points of the solvents, helping remove any remaining traces.
Direct vs indirect method:
- Direct method: The solvent comes into direct contact with the hydrated beans.
- Indirect method: The beans soak in water first. The caffeine-containing water is separated, treated with solvent and then returned to the beans so they can reabsorb flavour compounds.
Fun fact:
Decaffeination happens before roasting and typically removes around 97% or more of the original caffeine. Decaf is therefore low in caffeine, but not necessarily completely caffeine-free.
2. Swiss Water Process:




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